1,2-Bis(phenylsulfonyl)ethylene (BPSE): A Potent Radical C2 Synthon Available in the Radical and Electron-Transfer-Based Organic Synthesis - Université de Bordeaux
Article Dans Une Revue (Article De Synthèse) Synthesis: Journal of Synthetic Organic Chemistry Année : 2024

1,2-Bis(phenylsulfonyl)ethylene (BPSE): A Potent Radical C2 Synthon Available in the Radical and Electron-Transfer-Based Organic Synthesis

Shuhei Sumino
Ilhyong Ryu
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Frédéric Robert

Résumé

In this Short Review, we discuss radical reactions using 1,2-bis(phenylsulfonyl)ethylene (BPSE), which has drawn significant attention as a versatile building block for (phenylsulfonyl)ethenylation. Regardless of its E or Z form, BPSE exhibits reliable reactivity towards the attack of alkyl and aryl radicals in order to function as a reliable radical C2 synthon
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hal-04770055 , version 1 (06-11-2024)

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Shuhei Sumino, Ilhyong Ryu, Yannick Landais, Frédéric Robert. 1,2-Bis(phenylsulfonyl)ethylene (BPSE): A Potent Radical C2 Synthon Available in the Radical and Electron-Transfer-Based Organic Synthesis. Synthesis: Journal of Synthetic Organic Chemistry, 2024, PSRC-10 (10th Pacific Symposium on Radical Chemistry), 56 (21), pp.3233-3246. ⟨10.1055/s-0043-1775374⟩. ⟨hal-04770055⟩
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